Switchable asymmetric bio-epoxidation of α,β-unsaturated ketones.
نویسندگان
چکیده
Efficient asymmetric bio-epoxidation of electron-deficient α,β-unsaturated ketones was realized via a tandem reduction-epoxidation-dehydrogenation cascade, which proceeds in a switchable manner to afford either chiral epoxy ketones or allylic epoxy alcohols with up to >99% yield and >99%ee.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 6 شماره
صفحات -
تاریخ انتشار 2016