Switchable asymmetric bio-epoxidation of α,β-unsaturated ketones.

نویسندگان

  • Yu-Chang Liu
  • Zhong-Liu Wu
چکیده

Efficient asymmetric bio-epoxidation of electron-deficient α,β-unsaturated ketones was realized via a tandem reduction-epoxidation-dehydrogenation cascade, which proceeds in a switchable manner to afford either chiral epoxy ketones or allylic epoxy alcohols with up to >99% yield and >99%ee.

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عنوان ژورنال:
  • Chemical communications

دوره 52 6  شماره 

صفحات  -

تاریخ انتشار 2016